Preheat and prep pans: Heat the oven to 425°F (220°C). Line two sheet pans with parchment for easy cleanup.
Prep the chicken: Pat chicken dry.
Slice thick breasts horizontally to create even cutlets, about 1/2 to 3/4 inch thick. This helps them cook quickly and evenly.
Season the chicken: In a bowl, combine 1.5 tablespoons olive oil, half the minced garlic, 1/2 teaspoon salt, 1/2 teaspoon pepper, and Italian seasoning. Add lemon zest.
Toss chicken to coat.
Season the broccoli: On the second sheet pan, toss broccoli with 1.5 tablespoons olive oil, remaining garlic, 1/2 teaspoon salt, and 1/2 teaspoon pepper. Spread into an even layer.
Roast: Place broccoli on the top rack and chicken on the lower rack. Roast 10 minutes.
Add Parmesan layer: Remove both pans.
Sprinkle half the Parmesan over the chicken and half over the broccoli. If using, drizzle melted butter over the chicken for extra flavor.
Finish roasting: Return to the oven for 8–10 more minutes, until chicken reaches 165°F (74°C) internal temperature and broccoli edges are lightly crisp.
Add lemon and parsley: Squeeze lemon juice over both pans. Sprinkle with parsley.
Taste and adjust salt and pepper as needed.
Portion for meal prep: Divide into 4–5 containers. Each portion gets chicken, a big scoop of broccoli, and an optional serving of rice, quinoa, or pasta. Sprinkle any remaining Parmesan on top.
Cool before sealing: Let containers cool 15–20 minutes before closing to prevent steam buildup and sogginess.